{"id":1001,"date":"2007-09-22T19:35:02","date_gmt":"2007-09-22T22:35:02","guid":{"rendered":"https:\/\/www.gluon.com.br\/blog\/2007\/09\/22\/fluoreto-tetrabutil\/"},"modified":"2015-04-08T11:56:44","modified_gmt":"2015-04-08T11:56:44","slug":"fluoreto-tetrabutil","status":"publish","type":"post","link":"https:\/\/www.gluon.com.br\/blog\/2007\/09\/22\/fluoreto-tetrabutil\/","title":{"rendered":"Fluoreto de tetrabutilam\u00f4nio (mol\u00e9cula sedenta)"},"content":{"rendered":"<p>O \u00edon fluoreto \u00e9 muito importante na qu\u00edmica sint\u00e9tica, principalmente por poder ser usado para quebrar silil \u00e9teres (\u00e9teres com sil\u00edcio no lugar de carbono). O fluoreto \u00e9 famoso por reter \u00e1gua, portanto uma solu\u00e7\u00e3o anidra de fluoreto de tetrabutilam\u00f4nio (TBAF) (em THF) conter\u00e1 em torno de 5% de \u00e1gua. Quanto menos \u00e1gua existir no meio, mais livre estar\u00e1 \u00e2nion fluoreto, o que resultar\u00e1 em um sistema mais reativo do que o hidratado.<br \/>\n<img src='https:\/\/www.gluon.com.br\/blog\/wp-content\/uploads\/2007\/09\/tbaf.gif' alt='tetrabutil amonio' \/><br \/>\n<strong><a href=\"http:\/\/scienceblogs.com\/moleculeoftheday\/2006\/12\/tetrabutylammonium_fluoride_fl.php\">http:\/\/scienceblogs.com\/moleculeoftheday\/2006\/12\/tetrabutylammonium_fluoride_fl.php<\/a><\/strong><\/p>\n<p><small>Original (English) content from Molecule of the Day (<strong><a href=\"http:\/\/scienceblogs.com\/moleculeoftheday\">http:\/\/scienceblogs.com\/moleculeoftheday<\/a><\/strong>). Content translated with permission, but portuguese text not reviewed by the original author. Please do not distribute beyond this site without permission from both author and translator. <\/small><\/p>\n","protected":false},"excerpt":{"rendered":"<p>O \u00edon fluoreto \u00e9 muito importante na qu\u00edmica sint\u00e9tica, principalmente por poder ser usado para quebrar silil \u00e9teres (\u00e9teres com sil\u00edcio no lugar de carbono). O fluoreto \u00e9 famoso por reter \u00e1gua, portanto uma solu\u00e7\u00e3o anidra de fluoreto de tetrabutilam\u00f4nio (TBAF) (em THF) conter\u00e1 em torno de 5% de \u00e1gua. Quanto menos \u00e1gua existir no meio, mais livre estar\u00e1 \u00e2nion fluoreto, o que resultar\u00e1 em um sistema mais reativo do que o hidratado. http:\/\/scienceblogs.com\/moleculeoftheday\/2006\/12\/tetrabutylammonium_fluoride_fl.php Original (English) content from Molecule of the Day (http:\/\/scienceblogs.com\/moleculeoftheday). Content translated with permission, but portuguese text not reviewed by the original author. Please do not distribute <\/p>\n","protected":false},"author":1,"featured_media":5915,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[33],"tags":[],"class_list":["post-1001","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-mdd","has_thumb"],"aioseo_notices":[],"amp_enabled":true,"_links":{"self":[{"href":"https:\/\/www.gluon.com.br\/blog\/wp-json\/wp\/v2\/posts\/1001","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.gluon.com.br\/blog\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.gluon.com.br\/blog\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.gluon.com.br\/blog\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.gluon.com.br\/blog\/wp-json\/wp\/v2\/comments?post=1001"}],"version-history":[{"count":1,"href":"https:\/\/www.gluon.com.br\/blog\/wp-json\/wp\/v2\/posts\/1001\/revisions"}],"predecessor-version":[{"id":5916,"href":"https:\/\/www.gluon.com.br\/blog\/wp-json\/wp\/v2\/posts\/1001\/revisions\/5916"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.gluon.com.br\/blog\/wp-json\/wp\/v2\/media\/5915"}],"wp:attachment":[{"href":"https:\/\/www.gluon.com.br\/blog\/wp-json\/wp\/v2\/media?parent=1001"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.gluon.com.br\/blog\/wp-json\/wp\/v2\/categories?post=1001"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.gluon.com.br\/blog\/wp-json\/wp\/v2\/tags?post=1001"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}